首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   8599篇
  免费   1506篇
  国内免费   574篇
化学   2361篇
晶体学   36篇
力学   829篇
综合类   334篇
数学   3193篇
物理学   3926篇
  2024年   14篇
  2023年   140篇
  2022年   269篇
  2021年   396篇
  2020年   282篇
  2019年   229篇
  2018年   191篇
  2017年   345篇
  2016年   407篇
  2015年   301篇
  2014年   538篇
  2013年   674篇
  2012年   570篇
  2011年   532篇
  2010年   494篇
  2009年   578篇
  2008年   584篇
  2007年   609篇
  2006年   503篇
  2005年   426篇
  2004年   352篇
  2003年   361篇
  2002年   308篇
  2001年   249篇
  2000年   251篇
  1999年   183篇
  1998年   178篇
  1997年   145篇
  1996年   114篇
  1995年   71篇
  1994年   78篇
  1993年   74篇
  1992年   37篇
  1991年   31篇
  1990年   34篇
  1989年   16篇
  1988年   16篇
  1987年   12篇
  1986年   21篇
  1985年   16篇
  1984年   13篇
  1982年   7篇
  1981年   8篇
  1980年   2篇
  1979年   4篇
  1977年   5篇
  1971年   1篇
  1967年   1篇
  1959年   5篇
  1957年   1篇
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
41.
We present a model for tail wavelets, a phenomenon known as "echo" in the literature. The tail wavelet may appear in signal reconnaissances in the merger of binary compact objects, including black holes and neutron stars. We show that the dark matter surrounding the compact objects lead to a speculated tail wavelet following the main gravitational wave(GW). We demonstrate that the radiation pressure of the main wave is fully capable of pushing away the surrounding matter to some altitude, and splashing down of the matter excites the tail wavelet after ringing down of the main wave. We illustrate this concept in a simplified model, where numerical estimations are conducted on the specific distribution of dark matter outside the black hole horizon and the threshold values in accordance with observations. We study the full back reaction of the surrounding dark matter to the metric and find that the effect on to the tail wavelets is insignificant. We reveal the fine difference between the tail wavelets of a dressed and a bare black hole. We demonstrate that the tail wavelet can appear as a natural phenomenon in the frame of general relativity, without invoking modified gravities or quantum effects.  相似文献   
42.
43.
Poor water resistance and curing layer brittleness are significant challenges of greener soybean meal (SM) adhesive promotion and application. In this study an elastic network was built to crosslink the SM adhesive and improve the cured layer toughness of the resultant adhesive. Long-chain organo-sepiolite (OSEP) was first prepared by compound modification using KH-560 and KH-602 silane coupling agents. Triglycidylamine (TGA), a greener crosslinking agent with a large number of effective epoxy functional groups, was then synthesized. SM-based adhesives were fabricated using SM, OSEP and TGA. Results indicated that an elastic network was fabricated by the cross-linked reaction of SM, OSEP, and TGA. The elastic network effectively improved the toughness of the resultant adhesive. The wet shear strength of the plywood (PlyW) bonded by SM with 1% OSEP (SM/TGA/OSEP-1 adhesive) increased by 60% to 1.25 MPa relative to that of the SM/TGA adhesive. This study provided a greener, simple and cheap method improving the toughness and wet shear strength of SM-based adhesive, which contributes to the industrialized application of the product.  相似文献   
44.
We carried out the thermal curing of the copolymers of N-allylmaleimide (AMI) and 2-ethylhexyl acrylate (2EHA) using 1,3,4,6-tetra(2-mercaproethyl)glycoluril ( G1 ), 1,3,4,6-tetra(3-mercaptopropyl)glycoluril ( G2 ), 1,3,4,6-tetraallylglycoluril ( G3 ), triallylisocyanurate (TAIC), and pentaerythritol tetrakis(3-mercaptobutyrate) (PEMB) as the crosslinkers. Based on the results for the analysis of thiol–ene reactions monitored by IR spectroscopy, it was confirmed that the curing rate significantly depended on the combination of the used crosslinkers. The insoluble fraction after curing was more than 90% for the systems using the glycoluril crosslinkers, while the conversion of the allyl groups was suppressed due to the rigid structure of these crosslinkers. The heat resistance and the mechanical properties of the crosslinked polymers were investigated by thermogravimetric analysis, differential scanning calorimetry, dynamic mechanical analysis, and mechanical tensile tests. For the products cured using the glycoluril crosslinkers, the glass transition temperature (Tg) and the maximum temperature of thermal decomposition (Tmax) were 54–59 °C and 395–409 °C, respectively, being higher than those for the cured product prepared with PEMB and TAIC as the conventional crosslinkers. The elasticity (75–139 MPa), the maximum strength (3.0–4.1 MPa), and the adhesion strength (6.7–10.7 MPa) for the polymers cured with the glycoluril crosslinkers, determined by the mechanical tensile and single lap-shear adhesion tests, were higher than those for cured materials produced with PEMB. Thus, the thermal and mechanical properties of the maleimide copolymers were efficiently enhanced by crosslinking using the rigid glycoluril compounds. © 2020 Wiley Periodicals, Inc. J. Polym. Sci. 2020 , 58, 923–931  相似文献   
45.
A number of synthetic hydrogels suffer from low mechanical strength. Despite of the recent advances in the fabrication of tough hydrogels, it is still a great challenge to simultaneously construct high stretchability, and self-adhesive and self-healing capability in a hydrogel. Herein, a new type of double network hydrogel was prepared based on irreversible cross-linking of polyacrylamide chains and Schiff-base reversible cross-linking between glycidyl methacrylate-grafted ethylenediamine and oxidized sodium alginate (OSA). The combination of both cross-linkings and their synergistic effect provided a novel hydrogel with high strength, stretchable, rapid self-healing, and self-adhesiveness to different material. Besides, the hydrogels with diverse OSA content could maintain their original shapes after loading–unloading tensile test. The resulting hydrogel has a great potential in various fields for supporting and load-bearing substance.  相似文献   
46.
The implementation of covalent adaptable networks (CANs) in general resin system is becoming attractive. In this work, we propose a simple post-curing strategy based on the core-shell structured acrylate latex for the achievement on both the improved general performance and the CANs characteristics in latex films. The building to the CANs was relied on the introduction of 4,4′-diaminophenyl disulfide as the curing agent, which cured the acetoacetoxy decorated shell polymer through the ketoamine reaction. The metathesis reaction of aromatic disulfides in the crosslinking segments enabled the thermally induced dynamic behavior of the network as revealed in the stress relaxation tests by comparison with other diamine crosslinking agents without the incorporation of disulfide. The synergism of the dynamic crosslinking of the shell polymer and static crosslinking in the core polymer contributed to the improved mechanical strength (15 MPa, strain% = 250%) and the suppressed water adsorption (~1% in 24 h of soaking) of the latex film, which exhibited above 90% of recovery in both strength and strain from a cut-off film damage within 1 h at 80°C. Moreover, the cured latex film could be recycled, and 75% of the mechanical performance was regained after three fragmentation-hot-pressing cycles. These, in addition with the feasible and environmental friendly characteristics, suggest a sustainable paradigm toward the smart thermosetting latex polymers.  相似文献   
47.
48.
49.
随着供热计量系统的普及,系统可以根据负荷的变化进行调整,管网的阻力系数随即发生变化。对变动阻力系数进行优化辨识是了解供热管网实时运行状况的有效手段。提出一种基于流量监测数据的供热管网变动阻力系数优化辨识方法,并利用遗传算法进行求解。对洛阳市某小区供暖季管网实际运行数据进行验证,辨识结果的相对误差在5%以内。结果表明:该方法可以在只有流量观测数据时得到精度较高的供热管网变动阻力系数,为供热系统的运行调节提供指导。  相似文献   
50.
Wireless Sensor Networks (WSN) are widely used in recent years due to the advancements in wireless and sensor technologies. Many of these applications require to know the location information of nodes. This information is useful to understand the collected data and to act on them. Existing localization algorithms make use of a few reference nodes for estimating the locations of sensor nodes. But, the positioning and utilization of reference nodes increase the cost and complexity of the network. To reduce the dependency on reference nodes, in this paper, we have developed a novel optimization based localization method using only two reference nodes for the localization of the entire network. This is achieved by reference nodes identifying a few more nodes as reference nodes by the analysis of the connectivity information. The sensor nodes then use the reference nodes to identify their locations in a distributive manner using Artificial Hummingbird Algorithm (AHA). We have observed that the localization performance of the reported algorithm at a lower reference node ratio is comparable with other algorithms at higher reference node ratios.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号